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発表論文

発表論文

Dual Emission and Mechanofluorochromism of a V-shaped π-System Composed of Disulfonyl-substituted Dibenzocyclooctatetraenes: Nishida, Takanori; Ohta, Shinya; Xu, Feng; Shinohara, Kenta; Kamada, Takahiro; Akashi, Haruo; Takezaki, Makoto; Wakamatsu, Kan; Orita, Akihiro*
Org. Lett. , accepted..

Synthesis of diarylenynes by olefination of 1-arylpropyne with arylaldehyde and their optical properties: Shinohara, Kenta; Nishida, Takanori; Wada, Ryosuke; Peng, Lifen; Minoda, Yuju; Orita, Akihiro*; Otera, Junzo
Tetrahedron 2016, 72, 4427-4434..

One-Shot Double Amination of Sondheimer-Wong Diynes: Synthesis of Photoluminescent Dinaphthopentalenes: Feng Xu, lifen Peng, Kenta Shinohara, Takanori Nishida, Kan Wakamatsu, Motoyuki Uejima, Tohru Sato, Kazuyoshi Tanaka,* Norihiko Machida, Haruo Akashi,* Akihiro Orita,* Junzo Otera
Organic Letters 2015, 17, 3014-3017.

Syntheses and Physical Properties of Carbazole-Phthalonitrile-Hybridized Light-Emitting Materials: Kenta Shinohara, Yoshinori Suzuma, Takanori Nishida, Kan Wakamatsu, Akihiro Orita, Junzo Otera
ITE Transactions on Media Technology and Applications, 2015, 3(2), 114-120.

Extended Halogen Bonding between Fully Fluorinated Aromatic Molecules: Shigeki Kawai, Ali Sadeghi, Feng Xu, Lifen Peng, Akihiro Orita, Junzo Otera, Stefan Goedecker, and Ernst Meyer
ACS Nano, 2015, 9, 2574-2583.

Remarkable electron-withdrawing effect of the Ph2P(O)-ethynyl group: Ph2P(O)-ethynylsubstituted aryl halides and copper acetylides for tailor-made Sonogashira couplings: Lifen Peng, Feng Xu, Kenta Shinohara, Takanori Nishida, Kan Wakamatsu, Akihiro Orita* and Junzo Otera
Org. Chem. Front., 2015, 2, 248-252.

Substituted 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctenes: Syntheses, Properties and DFT Studies of Substituted Sondheimer-Wong Diynes: Feng Xu, Lifen Peng, Kenta Shinohara, Takamoto Morita, Suguru Yoshida, Takamitsu Hosoya, Akihiro Orita,* and Junzo Otera
J. Org. Chem. 2014, 79(23), 11592-11608.

Image Distortions of a Partially Fluorinated Hydrocarbon Molecule in Atomic Force Microscopy with Carbon Monoxide Terminated Tips: Nikolaj Moll,* Bruno Schuler, Shigeki Kawai, Feng Xu, Lifen Peng, Akihiro Orita, Junzo Otera, Alessandro Curioni, Mathias Neu, Jascha Repp, Gerhard Meyer, and Leo Gross
Nano Lett. 2014, 14 (11), 6127–6131.

Nucleophilic Substitution in 16pai-Anti-aromatic System: Synthesis of Heteroatom-substituted Dibenzopentalenes: Feng Xu, Lifen Peng, Kan Wakamatsu, Akihiro Orita,* and Junzo Otera*
Chem. Lett. 2014, 43(10), 1548-1550.

Selective Deprotection of Me3Si-/Ph2P(O)-protected Arylalkynes: Methyl Grignard Reagent-Promoted Dephosphorylation of Ph2P(O)-Protected Alkynes: Lifen Peng, Feng Xu, Kenta Shinohara, Akihiro Orita,* and Junzo Otera
Chem. Lett. 2014, 43(10), 1610-1612.

Dicarbazolyldicyanobenzenes as Thermally Activated Delayed Fluorescence Emitters: Effect of Substitution Position on Photoluminescent and Electroluminescent Properties: Bo Li, Hiroko Nomura, Hiroshi Miyazaki, Qisheng Zhang, Kou Yoshida, Yoshinori Suzuma, Akihiro Orita, Junzo Otera, and Chihaya Adachi Chem. Lett. (2014), 43(3), 319-321.

One-Pot Transformation of Ph2P(O)-Protected Ethynes: Deprotection Followed by Transition Metal-Catalyzed Coupling: Lifen Peng, Feng Xu, Yoshinori Suzuma, Akihiro Orita,* and Junzo Otera*
J. Org. Chem. 2013, 78, 12802-12808

Obtaining Detailed Structural Information about Supramolecular Systems on Surfaces by Combining High-Resolution Force Microscopy with ab Initio Calculations.: Kawai, Sigeki; Sadeghi, Ali; Xu, Feng; Lifen, Peng; Pawlak, Remy; Glatzel, Thilo; Willand, Alexander; Orita, Akihiro; Otera, Junzo; Goedecker, Stefan; Meyer, Ernst. ACS Nano (2013), 7(10), 9098?9105.

Efficient Synthesis of 9,10-Bis(phenylethynyl)anthracene Derivatives by Integration of Sonogashira Coupling and Double-Elimination Reactions.: Toyota, Shinji; Mamiya, Daiki; Yoshida, Rie; Tanaka, Ryo; Iwanaga, Tetsuo; Orita, Akihiro; Otera, Junzo. Synthesis (2013), 45(8), 1060-1068.

Photoinduced charge-transfer dynamics of sequentially aligned donor?acceptor systems in an ionic liquid.: Muramatsu, Masayasu; Katayama, Tetsuro; Ito, Syoji; Nagasawa, Yutaka; Matsuo, Daisuke; Suzuma, Yoshinori; Peng, Lifen; Orita, Akihiro; Otera, Junzo; Miyasaka, Hiroshi. Photochemical & Photobiological Sciences (2013), 12, 1885-1894.

Dihalo-Substituted Dibenzopentalenes: Their Practical Synthesis and Transformation to Dibenzopentalene Derivatives.: Xu, Feng; Peng, Lifen; Orita, Akihiro; Otera, Junzo. Organic Letters (2012), 14(15), 3970?3973.

Synthesis and Properties of Anthrylene-Substituted Phenyleneethynylene Dyes Having Amino/Cyano Group(s) and Their Application to Dye-Sensitized Solar Cells.: Yang, Xin; Kajiyama, Shingo; Fang, Jing-Kun; Xu, Feng; Uemura, Yu; Koumura, Nagatoshi; Hara, Kohjiro; Orita, Akihiro; Otera, Junzo. Bulletin of the Chemical Society of Japan (2012), 85(6), 687-697.

Ph2P(O) Group for Protection of Terminal Acetylenes.: Yang, Xin; Matsuo, Daisuke; Suzuma, Yoshinori; Fang, Jing-Kun; Xu, Feng; Orita, Akihiro; Otera, Junzo; Kajiyama, Shingo; Koumura, Nagatoshi; Hara, Kohjiro. Synlett (2011), (16), 2402-2406.

Synthesis and Properties of 9,10-Anthrylene-substituted Phenyleneethynylene Dyes for Dye-sensitized Solar Cell.: Yang, Xin; Fang, Jing-Kun; Suzuma, Yoshinori; Xu, Feng; Orita, Akihiro; Otera, Junzo; Kajiyama, Shingo; Koumura, Nagatoshi; Hara, Kohjiro. Chemistry Letters (2011), 40(6), 620-622.

Fluoro-Substituted Phenyleneethynylenes: Acetylenic n-type Organic Semiconductors.: Matsuo, Daisuke; Yang, Xin; Hamada, Akiko; Morimoto, Kyo; Kato, Takuji; Yahiro, Masayuki; Adachi, Chihaya; Orita, Akihiro; Otera, Junzo. Chemistry Letters (2010), 39(12), 1300?1302.

Synthesis and Spectroscopic Study of Phenylene-(poly)ethynylenes Substituted by Amino or Amino/Cyano Groups at Terminal(s): Electronic Effect of Cyano Group on Charge-transfer Excitation of Acetylenic π-Systems.: Fang, Jing-Kun; An, De-Lie; Wakamatsu, Kan; Ishikawa, Takeharu; Iwanaga, Tetsuo; Toyota, Shinji; Akita, Shin-ichi; Matsuo, Daisuke; Orita, Akihiro; Otera, Junzo. Tetrahedron (2010), 66(29), 5479?5485.

DFT Study on Activation of Carbon Dioxide by Dimethyltin Dimethoxide for Synthesis of Dimethyltin Carbonate.: Miyake, Nobuhisa; Nagahara, Hajime; Bijanto, Budianto; Wakamatsu, Kan; Orita, Akihiro; Otera, Junzo. Organometallics 2010, 29(5), 1290?1295; Organometallics 2010, 29 (13), 3062.

Synthesis and Applications of Novel Fluoroalkyl End-Capped Cooligomers Containing Diphenylacetylene Segments: A New Approach to the Surface Arrangement of Diphenylacetylene Segments on the Traditional Organic Polymer.: Mugisawa, Masaki; Orita, Akihiro; Otera, Junzo; Sawada, Hideo. Polymers Advanced Technologies (2010), 21(3), 158-163.

Synthesis and Spectroscopic Study of Diphenylamino-Substituted Phenylene-(poly)ethynylenes: Remarkable Effect of Acetylenic Conjugation Modes.: Fang, Jing-Kun; An, De-Lie; Wakamatsu, Kan; Ishikawa, Takeharu; Iwanaga, Tetsuo; Toyota, Shinji; Matsuo, Daisuke; Orita, Akihiro; Otera, Junzo. Tetrahedron Letters (2010), 51(6), 917-920.

マイクロリアクターを利用した機能性有機化合物の合成: 折田明浩, 大寺純蔵, 高分子 2010, 59, 593?594.

フッ化アルキル基を有するルイス酸の合成とそれを用いた触媒反応: 折田明浩, Organometallic News 2010, 2?7.

Chemistry of Anthracene-Acetylene Oligomers. XIV. Convenient Synthesis of Anthrylethynes by Double Elimination Reaction from Aldehydes and Sulfones.: Toyota, Shinji; Azami, Rie; Iwanaga, Tetsuo; Matsuo, Daisuke; Orita, Akihiro; Otera, Junzo. Bulletin of the Chemical Society of Japan (2009), 82(10), 1287-1291.

Synthesis of 2,5-Diaryloxazoles through van Leusen Reaction and Copper-Mediated Direct Arylation.: Yoshimizu, Tomoki; Satoh, Tetsuya; Hirano, Koji; Matsuo, Daisuke; Orita, Akihiro; Otera, Junzo; Miura, Masahiro. Tetrahedron Letters (2009), 50(26), 3273-3276.

Synthesis and Spectroscopic Study of Silacyclyne-Substituted Phenyleneethynylenes.: Mao, Guoliang; Orita, Akihiro; Matsuo, Daisuke; Hirate, Takayoshi; Iwanaga, Tetsuo; Toyota, Shinji; Otera, Junzo. Tetrahedron Letters (2009), 50(24), 2860-2864.

Blue Emitting Fluorophores of Phenyleneethynylenes Substituted by Diphenylethenyl Terminal Groups for Organic Light-Emitting Diodes.: Mao, Guoliang; Orita, Akihiro; Fenenko, Larysa; Yahiro, Masayuki; Adachi, Chihaya; Otera, Junzo. Materials Chemistry and Physics (2009), 115(1), 378-384.

Vibrational CD Spectroscopy as a Powerful Tool for Stereochemical Study of Cyclophynes in Solution.: An, De-Lie; Chen, Qiang; Fang, Jing-Kun; Yang, Hong; Orita, Akihiro; Miura, Nobuaki; Nakahashi, Atsufumi; Monde, Kenji; Otera, Junzo. Tetrahedron Letters (2009), 50(15), 1689-1692.

Metallocene Bis(perfluoroalkanesulfonate)s as Air-Stable Cationic Lewis Acids.: Qiu, Renhua; Zhang, Guoping; Xu, Xinhua; Zou, Kangbin; Shao, Lingling: Fang, Dawei; Li, Yinhui; Orita, Akihiro; Saijo, Ryosuke; Mineyama, Hidetaka; Suenobu, Tomoyoshi; Fukuzumi, Shunichi; An, De-Lie; Otera, Junzo. Journal of Organometallic Chemistry (2009), 694(9-10), 1524-1528.

Selective Tandem Inter/Intramolecular Eglington Coupling for Chiral Cyclophyne Synthesis.: An, De-Lie; Chen, Qiang; Zhang, Zhi-Yang; Yan, Hong; Fang, Jing-Kun; Su, Qiong; Dong, Wan-Rong; Orita, Akihiro; Otera, Junzo. Synthetic Communications (2009), 39(17), 3092-3100.

Facile Carbolithiation of Bent Alkyne without Catalyst. Tandem Route to Dibenzo[b,f]pentalenes from Dibenzocyclooctadiyne.: Babu, Govindarajulu; Orita, Akihiro; Otera, Junzo. Chemistry Letters (2008), 37(12), 1296-1297.

Evaluation of Tin-Oxygen Bond Association by Means of ab Initio Molecular Orbital Calculations.: Wakamatsu, Kan; Orita, Akihiro; Otera, Junzo. Organometallics (2008), 27, 1092-1097.

1,2-Diarylethenyl Sulfones: Readily-Prepared Masked Diarylethynes for Access to Aryleneethynylenes.: Doi, Takashi; Orita, Akihiro; Matsuo, Daisuke; Saijo, Ryosuke; Otera, Junzo. Synlett (2008), (1), 55-60.

Dependence of Lasing Threshold Power on Excitation Wavelength in Dye-Doped Cholesteric Liquid Crystals.: Wang, Yuanmin; Manabe, Takanobu; Takahashi, Yoichi; Ishikawa, Ken; Shao, Guang; Orita, Akihiro; Otera, Junzo; Takezoe, Hideo. Optics Communications (2007), 280(2), 408-411.

Synthesis and Photoluminescence Studies of Siloles with Arylene Ethynylene Strands.: Ding, Changhua; Babu, Govindarajulu; Orita, Akihiro; Hirate, Takayoshi; Otera, Junzo. Synlett (2007), (16), 2559-2563.

Integration of Solventless Reaction in a Multi-Step Process: Application to an Efficient Synthesis of PA-824.: Orita, Akihiro; Miwa, Kai; Uehara, Genta; Otera, Junzo. Advanced Synthesis & Catalysis (2007), 349(13), 2136-2144.

Importance of Molecular-Level Contacts under Solventless Conditions for Chemical Reactions and Self-Assembly.: Orita, Akihiro; Okano, Junji; Uehara, Genta; Jaing. Lasheng; Otera, Junzo. Bulletin of the Chemical Society of Japan (2007), 80(8), 1617-1623.

Convenient Synthesis of (1-Propynyl)arenes through a One-Pot Double Elimination Reaction, and Their Conversion to Enynes.: An, De-Lie; Zhang, Zhiyang; Orita, Akihiro; Mineyama, Hidetaka; Otera, Junzo. Synlett (2007), (12), 1909-1912.

Electrical Properties of 1,4-Bis(4-(phenylethynyl)phenylethynyl)benzene and its Application for Organic Light Emitting Diodes.: Fenenko, Larysa; Shao, Guang; Orita, Akihiro; Yahiro, Masayuki; Otera, Junzo; Svechnikov, Sergei; Adachi. Chihaya. Chemical Communications (2007), (22), 2278-2280.

Synthesis and Spectroscopic Studies of Various Arylene Ethynylene Fluorophores.: Shao, Guang; Orita, Akihiro; Taniguchi, Hisataka; Ishimaru, Kanako; Otera, Junzo. Synlett (2007), (2), 231-234.

Enantiopure Double-Helical Phenylene Ethynylene Cyclophynes with the 2,2’-Binaphthyl Template.: An, De-Lie; Zhang, Ying-Jun; Chen, Qiang; Zhao, Wen-Ying; Yan, Hong; Orita, Akihiro; Otera, Junzo. Chemistry ? An Asian Journal (2007), 2(10), 1299-1304.

Synthesis and Spectroscopic Studies of Arylethynylsilanes.: Shao, Guang; Orita, Akihiro; Nishijima, Koji; Ishimaru, Kanako; Takezaki, Makoto; Wakamatsu, Kan; Gleiter, Rolf; Otera, Junzo. Chemistry ? An Asian Journal (2007), 2(4), 489-498.

Elimination Strategy for Aromatic Acetylenes.: Orita, Akihiro; Otera, Junzo. Chemical Reviews (2006), 106(12), 5387-5412.

Optical and Electrical Properties of Bis(4-(phenylethynyl)phenyl)ethynes and Their Application to Organic Field-effect Transistors.: Oyamada, Takahito; Shao, Guang; Uchiuzou, Hiroyuki; Nakanotani, Hajime; Orita, Akihiro; Otera, Junzo; Yahiro, Masayuki; Adachi, Chihaya. Jpnanese Journal of Applied Physics (2006), 45, L1331-L1333.

Photoluminescence Enhancement in Tetrakis(arylethynyl)silanes.: Shao, Guang; Orita, Akihiro; Nishijima, Koji; Ishimaru, Kanako; Takezaki, Makoto; Wakamatsu, Kan; Otera, Junzo. Chemistry Letters (2006), 35(11), 1284-1285.

One-Shot Double Elimination Process: A Practical and Concise Protocol for Diaryl Acetylenes.: Orita, Akihiro; Tanisguchi, Hisataka; Otera, Junzo. Chemistry ? An Asian Journal (2006), 1(3), 430-437.

Fluorophilicity Switch by Solvation.: Orita, Akihiro; Man-e, Sumiyo; Otera, Junzo. Journal of the American Chemical Society (2006), 128(13), 4182-4183.

Organotin perfluorooctanesulfonates as air-stable Lewis acid catalysts: Synthesis, Characterization, and Catalysis.: An, De-Lie; Peng, Zhihong; Orita, Akihiro; Kurita, Akinobu; Man-e, Sumiyo; Ohkubo, Kei; Li, Xingshu; Fukuzumi, Shunichi; Otera, Junzo. Chemistry-A European Journal (2006), 12(6), 1642-1647.

Rate Acceleration of Organic Reaction by Immediate Solvent Evaporation.: Orita, Akihiro; Uehara, Genta; Miwa, Kai; Otera, Junzo. Chemical Communications (2006), 4729-4731.

Double Elimination Protocol for Arylene Ethynylenes.: Otera, Junzo. Pure and Applied Chemistry (2006), 78, 731-748.

Novel synthesis of 2-aryl and 2,3-disubstituted indoles by modified double elimination protocol.: Babu, Govibdarajulu; Orita, Akihiro; Otera, Junzo. Organic Letters (2005), 7(21), 4641-4643.

Double elimination protocol for the synthesis of arylene ethynylenes containing heteroaromatic rings.: Orita, Akihiro; Ye, Fangguo; Babu, Govindarajulu; Ikemoto, Tomohiro; Otera, Junzo. Canadian Journal of Chemistry (2005), 83(6-7), 716-727.

A cationic distannoxane catalyst. Synthesis and applications to carbon-carbon bond forming reactions.: Li, Xingshu; Kurita, Akinobu; Man-e, Sumiyo; Orita, Akihiro; Otera, Junzo. Organometallics (2005), 24, 2567-2569.

Fluorous distannoxane-catalyzed acetylation of alcohols in heterogeneous single fluorous solvent system.: Peng, Zhihong; Orita, Akihiro; An, Delie; Otera, Junzo. Tetrahedron Letters (2005), 46(18), 3187-3189.

Synthesis and properties of 1,6,7,12,13,18,19,24-octamethylacenaphthyleno [b,l]tetraphenylene.: Elliott, Eric L.; Orita, Akihiro; Hasegawa, Daiki; Gantzel, Peter; Otera, Junzo; Siegel, Jay S. Organic & Biomolecular Chemistry (2005), 3, 581-583.

Double elimination protocol for access to pyridine-containing arylene-ethynylenes.: Orita, Akihiro; Nakano, Takehiko; Yokoyama, Taisaku; Babu, Govindarajulu; Otera, Junzo. Chemistry Letters (2004), 33(10), 1298-1299.

Metal-assisted assembly of pyridine-containing arylene ethynylene strands to enantiopure double helicates.: Orita, Akihiro; Nakano, Takehiro; An, De-Lie; Tanikawa, Kazumi; Wakamatsu, Kan; Otera, Junzo. Journal of the American Chemical Society (2004), 126(33), 10389-10396.

Double elimination protocol for convenient synthesis of dihalodiphenylacetylenes: versatile building blocks for tailor-made phenylene-ethynylenes.: Orita, Akihiro; Miyamamoto, Kazuhiko; Nakashima, Mikio; Ye, Fangguo; Otera. Junzo. Advanced Synthesis & Catalysis (2004), 346(7), 767-776.

High birefringent bisdiynes and hexatriynes based on double elimination of β-substituted sulfones.: Ye, Fangguo; Orita, Akihiro; Yaruva, Jayamma; Hamada, Tatsuya; Otera, Junzo. Chemistry Letters (2004), 33(5), 528-529.

Intermittent molecular shuttle as a binary switch.: Jiang, Lasheng; Okano, Junji; Orita, Akihiro; Otera, Junzo. Angewandte Chemie International Edition (2004), 43(16), 2121-2124.

Rate acceleration of the reaction between solid reactants by premixing in solution: application to the efficient synthesis of a [2]rotaxane.: Orita, Akihiro; Okano, Junji; Tawa, Yoshiki; Jiang, Lasheng; Otera, Junzo. Angewandte Chemie International Edition (2004), 43(28), 3724-3728.

Integrated Chemical Processes; In “Frontier of Robotics and Microchemistry”,: Orita. Akihiro; Otera, Junzo. Kagaku Dojin (2004), p48-57.

Compaction of multi-step chemical process.: Orita. Akihiro; Nagano, Yoshifumi; Otera, Junzo. Chemical Industry (in Japanese) (2004), 55, 371-381.

Assessment of fluoroalkyltin compounds as fluorous Lewis acid catalysts: Imakura, Yasuo; Nishiguchi, Satoru; Orita, Akihiro; Otera, Junzo. Applied Organometallic Chemistry (2003), 17(10), 795-799.

Unusual carbonyl differentiation in the Lewis acid-catalyzed allylation of aldehydes with tetraallyltin. Applications to parallel recognition and shotgun process.: Nagano, Yoshifumi; Orita, Akihiro; Otera, Junzo. Bulletin of the Chemical Society of Japan (2003), 76(11), 2183-2189.

Method For Producing Oxazolidin-2-One Derivative.: Otera, Junzo; Furukawa, Yoshiro; Yoshimoto, Hiroshi. Japan Patent 2003-206282

Double elimination protocol for access to unsymmetrically substituted aromatic polyynes starting from sulfones and aldehydes.: Ye, Fangguo; Orita, Akihiro; Doumoto, Atsushi; Otera, Junzo. Tetrahedron (2003), 59(30), 5635-5643.

Diversification of shotgun process.: Nagano, Yoshifumi; Orita, Akihiro; Otera, Junzo. Tetrahedron (2003), 59(29), 5569-5578.

High atom efficiency in Sc(OTf)3-catalyzed allylation of aldehydes with tetraallyltin.: Nagano, Yoshifumi; Orita, Akihiro; Otera, Junzo. Advanced Synthesis & Catalysis (2003), 345(5), 643-646.

Quantitative Evaluation of Lewis Acidity of Metal Ions with Different Ligands and Counterions in Relation to the Promoting Effects of Lewis Acids on Electron Transfer Reduction of Oxygen.: Ohkubo, Kei; Menon, Saija C.; Orita, Akihiro; Otera, Junzo; Fukuzumi, Shunichi. Journal of Organic Chemistry (2003), 68(12), 4720-4726.

(R)-2,2'-Bis{[5-(2-phenylethynyl)thienyl]ethynyl}-1,1'-binaphthyl.: Loehr, Sandra; Yonemura, Makiko; Orita, Akihiro; Imai, Nobuyuki; Akashi, Haruo; Otera, Junzo. Acta Crystallographica, Section E: Structure Reports Online (2003), E59(5), o594-o595.

Shotgun process through differentiation of aliphatic and aromatic aldehyde functions: The first synthesis of ferulic acid hexan-3-onyl ether.: Nagano, Yoshifumi; Orita, Akihiro; Otera, Junzo. Synlett (2003), (5), 684-688.

Automatic synthesis apparatus MEDLEY.: Otera, Junzo; Orita, Akihiro. Purosesu Kemisutori no Shintenkai (2003), 172-183.

Double elimination protocol for access to unsymmetrical bis(phenylethynyl)benzenes.: Orita, Akihiro; Ye, Fangguo; Doumoto, Atsushi; Otera, Junzo. Chemistry Letters (2003), 32(1), 104-105.

Hexacarbonyldicobalt(0) complex of 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene, [(eta2-C16H8)Co2(CO)6].: Orita, Akihiro; Jiang, Lasheng; Ye, Fangguo; Imai, Nobuyuki; Akashi, Haruo; Otera, Junzo. Acta Crystallographica, Section E: Structure Reports Online (2002), E58(12), m748-m749.

Fluorous biphasic esterification directed towards ultimate atom efficiency.: Xiang, Jiannan; Orita, Akihiro; Otera, Junzo. Angewandte Chemie, International Edition (2002), 41(21), 4117-4119.

A hexacarbonyldicobalt(0) complex of a 'magazine-rack' molecule, [(eta2-C32H20)Co2(CO)6]_CH22Cl2.: Orita, Akihiro; Jiang, Lasheng; Ye, Fangguo; Imai, Nobuyuki; Akashi, Haruo; Otera, Junzo. Acta Crystallographica, Section E: Structure Reports Online (2002), E58(11), m681-m683.

Design of chemical processes for automated synthesis.: Otera, Junzo. Laboratory Automation in the Chemical Industries (2002), 235-263.

Combined Lewis acid catalysts in shotgun process: a convenient synthesis of the female sex pheromone of the red-bollworm moth.: Nagano, Yoshifumi; Orita, Akihiro; Otera, Junzo. Tetrahedron (2002), 58(41), 8211-8217.

Parallel recognition by kinetic control with imino aldehyde substrates that are prone to redistribution.: Orita, Akihiro; Nagano, Yoshifumi; Nakazawa, Koichi; Otera, Junzo. Advanced Synthesis & Catalysis (2002), 344(5), 548-555.

Solventless reaction dramatically accelerates supramolecular self-assembly: Orita, Akihiro; Jiang, Lasheng; Nakano, Takehiko; Ma, Nianchun; Otera, Junzo Chemical Communications (Cambridge, United Kingdom) (2002), (13), 1362-1363

Sulfoximine version of double elimination protocol for synthesis of chiral acetylenic cyclophanes: Orita, Akihiro; An, De Lie; Nakano, Takehiko; Yaruva, Jayamma; Ma, Nianchun; Otera, Junzo Chemistry--A European Journal (2002), 8(9), 2005-2010.

Double elimination protocol for synthesis of 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene: Orita, Akihiro; Hasegawa, Daiki; Nakano, Takehiko; Otera, Junzo Chemistry--A European Journal (2002), 8(9), 2000-2004.

Synthesis and characterization of fluoroalkyldistannoxanes: Xiang, Jiannan; Orita, Akihiro; Otera, Junzo Journal of Organometallic Chemistry (2002), 648(1-2), 246-250.

Fluoroalkyldistannoxane catalysts for transesterification in fluorous biphase technology: Xiang, Jiannan; Orita, Akihiro; Otera, Junzo Advanced Synthesis & Catalysis (2002), 344(1), 84-90.

Novel .pi.-conjugated cyclophanes: magazine rack molecules: Orita, Akihiro; Jiang, Lasheng; Tsuruta, Madoka; Otera, Junzo Chemistry Letters (2002), (2), 136-137.

Enantiopure double-helical alkynyl cyclophanes: An, De Lie; Nakano, Takehiko; Orita, Akihiro; Otera, Junzo Angewandte Chemie, International Edition (2002), 41(1), 171-173.

A practical and green chemical process: fluoroalkyldistannoxane-catalyzed biphasic transesterification: Xiang, Jiannan; Toyoshima, Shinji; Orita, Akihiro; Otera, Junzo Angewandte Chemie, International Edition (2001), 40(19), 3670-3672.

Highly Powerful and Practical Acylation of Alcohols with Acid Anhydride Catalyzed by Bi(OTf)3: Orita, Akihiro; Tanahashi, Chiaki; Kakuda, Atsushi; Otera, Junzo Journal of Organic Chemistry (2001), 66(26), 8926-8934.

Quantitative evaluation of Lewis acidity of organotin compounds and the catalytic reactivity in electron transfer: Ohkubo, Kei; Suenobu, Tomoyoshi; Imahori, Hiroshi; Orita, Akihiro; Otera, Junzo; Fukuzumi, Shunichi Chemistry Letters (2001), (10), 978-979.

Highly efficient deacetylation by use of the neutral organotin catalyst [tBu2SnOH(Cl)]2: Orita, Akihiro; Hamada, Yuuki; Nakano, Takehiko; Toyoshima, Shinji; Otera, Junzo Chemistry--A European Journal (2001), 7(15), 3321-3327.

Automation of organic synthesis on the basis of integrated chemical process: Orita, Akihiro; Otera, Junzo Yuki Gosei Kagaku Kyokaishi (2001), 59(8), 732-741.

Integrated Chemical Process for Green Chemistry. One-Pot Synthesis of 3-Substituted 5-(b-Sulfonylvinyl)indoles by in situ Generation of Toxic Vinyl Sulfone: Orita, Akihiro; Katakami, Masataka; Yasui, Yutaka; Kurihara, Akio; Otera, Junzo Green Chemistry. (2001), 3, 13-16.

In search of practical esterification: Otera, Junzo Angewandte Chemie, International Edition (2001), 40(11), 2044-2045.

Lewis acid-promoted transesterification of N-acyl oxazolidinones under mild conditions: Orita, Akihiro; Nagano, Yoshifumi; Hirano, Junichi; Otera, Junzo Synlett (2001), (5), 637-639.

Integrated chemical process: convenient synthesis of enantiopure 2-hydroxymethyl-1,4-benzodioxane derivatives with iterative catalysis by CsF: Kitaori, Kazuhiro; Furukawa, Yoshiro; Yoshimoto, Hiroshi; Otera, Junzo Advanced Synthesis & Catalysis (2001), 343(1), 95-101.

One-pot preparation of 1,4-benzodioxanes as intermediates for .alpha.- and .beta.-adrenoceptor antagonists: Furukawa, Yoshiro; Kitaori, Kazuhiro; Yoshimoto, Hiroshi; Otera, Junzo Patent

Higher order association of distannoxane leading to novel sheet-like framework: Orita, Akihiro; Sakamoto, Katsumasa; Ikeda, Hiroshi; Xiang, Jiannan; Otera, Junzo Chemistry Letters (2001), (1), 40-41.

Comparison between Electron Transfer and Nucleophilic Reactivities of Ketene Silyl Acetals with Cationic Electrophiles: Fukuzumi, Shunichi; Ohkubo, Kei; Otera, Junzo Journal of Organic Chemistry (2001), 66(4), 1450-1454.

Integrated chemical process. Convergent strategy for an ortho-phenylene ethynylene skeleton by a one-pot double elimination method: Orita, Akihiro; Alonso, Emma; Yaruva, Jayamma; Otera, Junzo Synlett (2000), (9), 1333-1335.

Automated Synthesis: Utilization of MEDLEY in Synthetic Processes: Orita, Akihiro;Yasui, Yutaka; Otera, Junzo Organic Process Research & Development (2000), 4(5), 337-341.

Automated Synthesis: Development of a New Apparatus Friendly to Synthetic Chemists (MEDLEY): Orita, Akihiro; Yasui Yutaka; Otera, Junzo Organic Process Research & Development (2000), 4(5), 333-336.

Preparation of 1-acyloxy-3-halo-2-propanols, their sulfonates, and epihalohydrins: Otera, Junzo; Furukawa, Yoshiro; Yoshimoto, Hiroshi Patent

Highly Efficient and Versatile Acylation of Alcohols with Bi(OTf)3 as Catalyst: Orita, Akihiro; Tanahashi, Chiaki;Kakuda, Atsushi; Otera, Junzo Angewandte Chemie, International Edition (2000), 39(16), 2877-2879.

Cationic Organotin Clusters for Highly Efficient Alcohol Acetylation Catalysts: Durand, Sandrine; Sakamoto, Katsumasa; Fukuyama, Takahide; Orita, Akihiro; Otera, Junzo; Duthie, Andrew; Dakternieks, Dainis; Schulte, Marcus;Jurkschat, Klaus Organometallics (2000), 19(16), 3220-3223.

Synthesis and Structural Studies on Dimeric Organotin Cations: Sakamoto Katsumasa; Ikeda Hiroshi; Akashi Haruo; Fukuyama Takahide; Orita, Akihiro; Otera, Junzo Organometallics (2000), 19(16), 3242-3248.

Design of chemical process for automated synthesis: Orita, Akihiro; Otera, Junzo Kagaku Kogyo (2000), 51(2), 96-105.

Shotgun process: a practical treatment for simultaneous multiple reactions: Orita, Akihiro; Nagano, Yoshifumi; Nakazawa, Koichi; Otera, Junzo Synlett (2000), (5), 599-602.

[tBu2SnOH(Cl)]2 as a highly efficient catalyst for deacetylation: Orita, Akihiro; Sakamoto, Katsumasa; Hamada, Yuuki; Otera, Junzo Synlett (2000), (1), 140-142.

Process for the preparation of glycidyl ethers: Furukawa, Yoshiro; Kitaori, Kazuhiro; Yanagimoto, Tetsuya; Mikami, Masafumi; Yoshimoto, Hiroshi; Otera, Junzo Patent

Preparation of 3-amino-2-hydroxy-1-propyl ethers by etherification and amination: Furukawa, Yoshiro; Kitaori, Kazuhiro; Mikami, Masafumi; Yoshimoto, Hiroshi; Otera, Junzo Patent

CsF in organic synthesis. Regioselective nucleophilic reactions of phenols with oxiranes leading to enantiopure .beta.-blockers: Kitaori, Kazuhiro; Furukawa, Yoshiro; Yoshimoto, Hiroshi; Otera, Junzo Tetrahedron (1999), 55(50), 14381-14390.

Recent developments in the chemistry of spacer bridged distannoxanes: Schulte, Marcus; Mehring, Michael; Paulus, Ingo; Schurmann, Markus; Jurkschat, Klaus; Dakternieks, Dainis; Duthie, Andrew; Orita, Akihiro; Otera, Junzo Phosphorus, Sulfur, and Silicon and the Related Elements (1999), 150-151, 201-210.

Novel Dimeric Organotin Cations: Highly Effective Alcohol Acetylation Catalysts: Sakamoto, Katsumasa; Hamada, Yuuki; Akashi, Haruo; Orita, Akihiro; Otera, Junzo Organometallics (1999), 18(18), 3555-3557

Biodegradable resin compositions and their manufacture: Otera, Junzo; Yano, Toru; Sakuta, Nobuyuki Patent

Integrated chemical process: one-pot double elimination method for acetylenes: Orita, Akihiro; Yoshioka, Naonori; Struwe, Petra; Braier, Arnold; Beckmann, Anke; Otera, Junzo Chemistry - A European Journal (1999), 5(4), 1355-1363.

Spacer-bridged ladder compounds-syntheses, structures and synthetic applications: Mehring, Michael; Schurmann, Markus; Paulus, Ingo; Horn, Dagmar; Jurkschat, Klaus; Orita, Akihiro; Otera, Junzo; Dakternieks, Dainis; Duthie, Andrew Journal of Organometallic Chemistry (1999), 574(1), 176-192.

Mild and practical acylation of alcohols with esters or acetic anhydride under distannoxane catalysis: Orita, Akihiro; Sakamoto, Katsumasa; Hamada, Yuji; Mitsutome, Akihiro; Otera, Junzo Tetrahedron (1999), 55(10), 2899-2910.

Integrated chemical process. Construction of highly substituted allylic moieties from allylic sulfones in one-pot: Orita, Akihiro; Watanabe, Akihiro; Tsuchiya, Hiroshi; Otera, Junzo Tetrahedron (1999), 55(10), 2889-2898.

Preparation, reactivities, and NMR spectra of pentafluorophenyltin derivatives: Chen, Jian-Xie; Sakamoto, Katsumasa; Orita, Akihiro; Otera, Junzo Journal of Organometallic Chemistry (1999), 574, 58-65.

Unusual Preference for Ketone and Reversal of Chemoselectivity in Lewis Acid-Catalyzed Aldol Reaction of Ketene Silyl Acetal: Chen, Jian-xie; Sakamoto, Katsumasa; Orita, Akihiro; Otera, Junzo Journal of Organic Chemistry (1998), 63(26), 9739-9745.

Parallel recognition by virtue of differentiation between carbonyls, acetals and enones: Chen, Jian-Xie; Sakamoto, Katsumasa; Orita, Akihiro; Otera, Junzo Tetrahedron (1998), 54(29), 8411-8420.

CsF in organic synthesis. A convenient synthesis of cyclopropano lactone from glycidyl nosylate: Kitaori, Kazuhiro; Mikami, Masfumi; Furukawa, Yoshiro; Yoshimoto, Hiroshi; Otera, Junzo Synlett (1998), (5), 499-500.

CsF in organic synthesis. The first and convenient synthesis of enantiopure bisoprolol by use of glycidyl nosylate: Kitaori, Kazuhiro; Furukawa, Yoshiro; Yoshimoto, Hiroshi; Otera, Junzo Tetrahedron Letters (1998), 39(20), 3173-3176.

Temperature-effected tuning of enantioselectivity in asymmetric catalysis: Otera, Junzo; Sakamoto, Katsumasa; Tsukamoto, Takao; Orita, Akihiro Tetrahedron Letters (1998), 39(20), 3201-3204.

Convenient preparation of enantiopure atenolol by means of preferential crystallization: Kitaori, Kazuhiro; Takehira, Yosikazu; Furukawa, Yoshiro; Yoshimoto, Hiroshi; Otera, Junzo Chemical and Pharmaceutical Bulletin (1998), 46(3), 505-507.

Parallel differentiated recognition of ketones and acetals: Chen, Jian-xie; Otera, Junzo Angewandte Chemie, International Edition (1998), 37(1/2), 91-93.

Parallel recognition by virtue of differentiation between ketone and aldehyde: Chen, Jian-Xie; Otera, Junzo Tetrahedron Letters (1998), 39(13), 1767-1770.

Distannoxane-Catalyzed Highly Selective Acylation of Alcohols: Orita, Akihiro; Mitsutome, Akihiro; Otera, Junzo Journal of Organic Chemistry (1998), 63(8), 2420-2421.

Process for the preparation of glycidyl ethers: Furukawa, Yoshiro; Kitaori, Kazuhiro; Yanagimoto, Tetsuya; Mikami, Masafumi; Yoshimoto, Hiroshi; Otera, Junzo Patent

Preparation of 3-amino-2-hydroxy-1-propyl ethers by etherification and amination: Furukawa, Yoshiro; Kitaori, Kazuhiro; Mikami, Masafumi; Yoshimoto, Hiroshi; Otera, Junzo Patent

Preparation of biodegradable hydroxycarboxylic acid copolymers: Otera, Junzo; Yano, Toru; Yamamoto, Hirokazu; Sakuda, Nobuyuki Patent

Organotin perchlorates as gentle Lewis acid catalysts in Mukaiyama reaction: Chen, Jian-Xie; Otera, Junzo Tetrahedron (1997), 53(42), 14275-14286.

CsF in organic synthesis. Inversion of secondary mesylates and tosylates: Otera, Junzo; Nakazawa, Koichi; Sekoguchi, Koichi; Orita, Akihiro Tetrahedron (1997), 53(40), 13633-13640.

Integrated chemical process. One-pot preparation of olefins by alkylation and desulfonylation: Orita, Akihiro; Watanabe, Akihiro; Otera, Junzo Chemistry Letters (1997), (10), 1025-1026.

Integrated chemical process. One-pot preparation of acetylenes by Peterson-sulfone elimination: Orita, Akihiro; Yoshioka, Naonori; Otera, Junzo Chemistry Letters (1997), (10), 1023-1024.

Metal ion-complexes of .alpha.,.beta.-unsaturated ketones acting as actual reactive species in Michael addition of ketene silyl acetal: Fukuzumi, Shunichi; Okamoto, Toshihiko; Yasui, Kiyomi; Suenobu, Tomoyoshi; Itoh, Shinobu; Otera, Junzo Chemistry Letters (1997), (7), 667-668.

Integrated chemical process: an extremely concise synthesis of vitamin A: Orita, Akihiro; Yamashita, Yasuo; Toh, Akiji; Otera, Junzo Angewandte Chemie, International Edition (1997), 36(7), 779-780.

SmI2-promoted conjugate reduction of .alpha.,.beta.-unsaturated esters and ketones studied in comparison with Mukaiyama-Michael reaction of ketene silyl acetal: Fujita, Yukihiro; Fukuzumi, Shunichi; Otera, Junzo Tetrahedron Letters (1997), 38(12), 2121-2124.

Mukaiyama-Michael reaction of cyclic ketene silyl acetals and enones. Importance of ring flexibility in electron transfer process: Fujita, Yukihiro; Fukuzumi, Shunichi; Otera, Junzo Tetrahedron Letters (1997), 38(12), 2117-2120.

A practical synthesis of optically active atenolol from chiral epichlorohydrin: Kitaori, Kazuhiro; Takehira, Yoshikazu; Furukawa, Yoshiro; Yoshimoto, Hiroshi; Otera, Junzo Chemical and Pharmaceutical Bulletin (1997), 45(2), 412-414.

Reversal of chemoselectivity in organotin Lewis acid-catalyzed reaction of ketene silyl acetal with aldehyde and .alpha.-enal: Chen, Jianxie; Otera, Junzo Synlett (1997), (1), 29-30.